You can use any wine but this is especially useful when you find yourself throwing away "old" wine or bits of bottles-it will still be perfectly good for making vinegar. I have no qualms about mixing red and white if common sense dictates doing so.
Some wines have preservatives. They will still make vinegar but it will take a good while. The older the vinegar gets the better the flavor. The acidity will vary.
You may observe something cloudy which may eventually form something that looks like this:
or this if it is white wine:
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